作者: Zhao, JJ (Zhao, Jiaji); Li, QD (Li, Qingduan); Liu, SJ (Liu, Shengjian); Cao, ZX (Cao, Zhixiong); Jiao, XC (Jiao, Xuechen); Cai, YP (Cai, Yue-Peng); Huang, F (Huang, Fei)

标题: Bithieno[3,4-dpyrrole-4,6-dione-Mediated Crystallinity in Large-Bandgap Polymer Donors Directs Charge Transportation and Recombination in Efficient Nonfullerene Polymer Solar Cells

来源出版物: ACS ENERGY LETTERS

卷: 5

期: 2

页: 367-375

DOI: 10.1021/acsenergylett.9b02842

出版年: FEB 2020

摘要: Solution-processed nonfullerene bulk-heterojunction (BHJ) polymer solar cells (PSCs), which are composed of polymer donors and organic acceptors, are proven to manifest promising performance and long-term stability. In this concise contribution, bithieno[3,4-c]pyrrole-4,6-dione (BiTPD), which is a TPD derivative but presents a large planar structure and strong electron-withdrawing ability, was used to construct a large-bandgap polymer donor PBiTPD. Results show that the polymer donor PBiTPD realized power conversion efficiency (PCE) as high as 14.2% in fullerene-free BHJ solar cells. Larger ionization potential value, more favorable face-on backbone orientation, and stronger crystallinity were concurrently obtained in PBiTPD. Correspondingly, improved and more balanced charge transportation; less nongeminate and trap-assisted recombination losses; and thus high fill factor (FF) of 67%, short-circuit current density (J(SC)) of 25.6 mA.cm(-2), and high open-circuit voltage (V-OC) of 0.83 V were concurrently achieved in PBiTPD-based devices. PBiTPD does clear the way for a novel and promising class of large-bandgap polymer donor candidates.

关键词

KeyWords Plus: DESIGN; ACCEPTOR

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