广东省高能动力与储能电池有机高分子功能材料工程实验室简介

广东省高能动力与储能电池有机高分子功能材料工程实验室(以下简称“工程实验室”)于2015年4月获广东省发展改革委批准立项建设。

工程实验室主要开展动力与储能电池用有机组分如有机电解质盐、有机溶剂及有机功能添加剂,以及高分子组分如凝胶聚合物、聚合物支撑体、电极粘结剂等功能材料的研究与开发,提高动力与储能电池的安全性及使用寿命。通过实验室的建设,为动力与储能电池产业提升新材料和应用新技术,同时培养动力与储能产业链的高级人才。

代表性成果:

1.张若昕、李伟善、张翠芬、刘建生、左晓希、吕东生、赵灵智、周邵云、李永坤、王姣丽,动力锂离子电池用功能电解质的产业化(广州天赐高新材料股份有限公司、华南师范大学、广州丰江电池新技术股份有限公司),2012,广州市科技进步二等奖

2.M. Z. Liu, L. D. Xing*, K. Xu, H. B. Zhou, J. L. Lan, C. Wang, W. S. Li, Deciphering the paradox between the Co-intercalation of sodium-solvent into graphite and its irreversible capacity, Energy Storage Materials, 2020, 26: 32–39

3.R. D. Guo, Y. X. Che, G. Y. Lan, J. L. Lan, J. H. Li, L. D. Xing, K. Xu*, W. Z. Fan, L. Yu, W. S. Li*, Tailoring Low-Temperature Performance of a Lithium-Ion Battery via Rational Designing Interphase on an Anode, ACS Appl. Mater. Interfaces, 2019, 11:38285-38293

4.J. L. Lan, Q. F. Zheng, H. B. Zhou, J. H. Li, L. D. Xing, K. Xu*, W. Z. Fan, Le, Yu, W. S. Li*, Stabilizing a High-Voltage Lithium-Rich Layered Oxide Cathode with a Novel Electrolyte Additive, ACS Appl. Mater. Interfaces, 2019, 11:28841−28850

5.Q. K. Zhang, K. Wang, X. S. Wang, Y. T. Zhong, M. Z. Liu, X. Liu*, K. Xu*, W. Z. Fan, L. Yu, W. S. Li*, Lithium Bis(oxalate)borate Reinforces the Interphase on Li-Metal Anodes, ACS Appl. Mater. Interfaces, 2019,11:20854-20863

6.S. P. Wu, Y. L. Lin, L. D. Xing, G. Z. Sun, H. B. Zhou*, K. Xu*, W. Z. Fan, L. Yu, W. S. Li*, Stabilizing LiCoO2/graphite at High Voltage with Electrolyte Additive, ACS Appl. Mater. Interfaces, 2019, 11:17940−17951

7.C. C. Ye, W. T. Tu, L. M. Yin, Q. F. Zheng, C. Wang, Y. T. Zhoung, Y. G. Zhang, Q. M. Huang, K. Xu*, W. S. Li*, Converting detrimental HF in electrolyte into a highly-fluorinated interphase on cathode, J. Mater. Chem. A, 2018, 6:17642 – 17652

8.B. Liao, X. L. Hu, M. Q. Xu*, H. Y. Li, L. Yu, W. Z. Fan, L. D. Xing, Y. H. Liao, W. S. Li*, Constructing Unique Cathode Interface by Manipulating Functional Groups of Electrolyte Additive for Graphite/LiNi0.6Co0.2Mn0.2O2 Cells at High Voltage, J. Phys. Chem. Lett. 2018, 9:3434-3445

9.Y. L. Lin, M. Q. Xu*, S. P. Wu, Y. Y. Tian, Z. G. Cao, L. D. Xing, W. S. Li*, Insight into the Mechanism of Improved Interfacial Properties between Electrodes and Electrolyte in the Graphite/LiNi0.6Mn0.2Co0.2O2 Cell via Incorporation of 4‑Propyl-[1,3,2]dioxathiolane-2,2-dioxide (PDTD), ACS Appl. Mater. Interfaces, 2018, 10, 16400−16409

10.Q. F. Zheng, L. D. Xing*, X. R. Yang, X. F. Li, C. C. Ye, K. Wang, Q. M. Huang, W. S. Li*, N‑Allyl‑N,N‑Bis(trimethylsilyl)amine as a Novel Electrolyte Additive to Enhance the Interfacial Stability of a Ni-Rich Electrode for Lithium-Ion Batteries, ACS Appl. Mater. Interfaces, 2018, 10:16843−16851